Dan,
It is a good idea to reference the Polyfiber manual when covering the wings. Years ago, I asked Ray Stits about covering the Bellanca wings at his Polyfiber booth at Oshkosh. At the time, he was covering a plywood covered horizontal stabilizer for one of the EAA's warbird restorations (a Corsair, I think). Anyway, I got to watch him go through the whole procedure.
As you said, the basic idea is to lay down some layers of Polybrush directly on the wing, then put the fabric on the wing - tacking it down as necessary to hold it in place. Then, using highly thinned Polybrush, apply the Polybrush to the fabric and work it down through the fabric. The thinned Polybrush will cause the underlying layers on the wing to soften and bond with the new, thinned olybrush and generating greater adhesion to the fabric. After it all dries out, you then follow the standard procedure in the book for adding additional Polybrush and finishing coats.
Apparently, in the old days when using cotton (or linen) fabric, this technique was not always used. Often the fabric was just laid on the bare wood and the dope applied to the top of the fabric and worked into the cotton with a brush. It seems that the cotton fibers acted like a tiny mops and the dope got liberally applied to the underlying wood, thus creating good adhesion between the fabric and the wood. Modern dacron type fabrics have a much tighter weave and tend to block the flow of normal dope through the fabric. Therefore, it is essential to put down starting layers of polybrush on the wood, then work the thinned polybrush into the polyfiber fabric.
If I recall correctly, analysis of the fatal mid-air disintegration of Steve Whitman's airplane showed that there was no underlying coat on the wing surfaces immediately ahead of the ailerons. Steve was a longtime mechanic and may have used the older cotton/dope approach to apply the dacron fabric on the wing. At any rate, the analysis that I read said that there was insufficient adhesion between the fabric and wing surface, even though the plane had flown for years. During the fatal flight, the fabric pulled loose from the wing surface just ahead of one aileron and puffed up into the airstream, blocking airflow to the aileron and inducing immediate, catastrophic aileron flutter that lead to the sudden destruction of both the aileron and wing.
So doing this operation correctly IS important.